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10.1038/ncomms8248 http://scihub22266oqcxt.onion/10.1038/ncomms8248 C4557361!4557361!26088017     free     free     free Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534       Nat+Commun 2015 ; 6 (ä): ä Nephropedia Template TP {{tp|p=26088017|t=2015. The solvation of electrons by an atmospheric-pressure plasma |pdf=|usr=}}{{26088017}} gab.com Text The solvation of electrons by an atmospheric-pressure plasma JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=26088017 #FOAvip Solvated electrons are typically generated by radiolysis or photoionization of solutes. While plasmas containing free electrons have been brought into contact with liquids in studies dating back centuries, there has been little evidence that electrons are solvated by this approach. Here we report direct measurements of solvated electrons generated by an atmospheric-pressure plasma in contact with the surface of an aqueous solution. The electrons are measured by their optical absorbance using a total internal reflection geometry. The measured absorption spectrum is unexpectedly blue shifted, which is potentially due to the intense electric field in the interfacial Debye layer. We estimate an average penetration depth of 2.5±1.0?nm, indicating that the electrons fully solvate before reacting through second-order recombination. Reactions with various electron scavengers including H+, NO2?, NO3? and H2O2 show that the kinetics are similar, but not identical, to those for solvated electrons formed in bulk water by radiolysis. Twit Text FOAVip The solvation of electrons by an atmospheric-pressure plasma ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=26088017 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=26088017 #FOAvip English Wikipedia <ref>{{Cite pmid|26088017}}</ref> The solvation of electrons by an atmospheric-pressure plasma #MMPMID26088017 Rumbach P; Bartels DM; Sankaran RM; Go DB Nat Commun 2015[]; 6 (ä): ä PMID26088017show ga Solvated electrons are typically generated by radiolysis or photoionization of solutes. While plasmas containing free electrons have been brought into contact with liquids in studies dating back centuries, there has been little evidence that electrons are solvated by this approach. Here we report direct measurements of solvated electrons generated by an atmospheric-pressure plasma in contact with the surface of an aqueous solution. The electrons are measured by their optical absorbance using a total internal reflection geometry. The measured absorption spectrum is unexpectedly blue shifted, which is potentially due to the intense electric field in the interfacial Debye layer. We estimate an average penetration depth of 2.5±1.0?nm, indicating that the electrons fully solvate before reacting through second-order recombination. Reactions with various electron scavengers including H+, NO2?, NO3? and H2O2 show that the kinetics are similar, but not identical, to those for solvated electrons formed in bulk water by radiolysis. äThe solvation of electrons by an atmospheric-pressure plasma (epmc).pdf DeepDyve Pubget Overpricing