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10.1038/ncomms8358

http://scihub22266oqcxt.onion/10.1038/ncomms8358
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C4557350!4557350!26082275
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suck abstract from ncbi


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pmid26082275      Nat+Commun 2015 ; 6 (ä): ä
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  • Surface determination through atomically resolved secondary-electron imaging #MMPMID26082275
  • Ciston J; Brown HG; D'Alfonso AJ; Koirala P; Ophus C; Lin Y; Suzuki Y; Inada H; Zhu Y; Allen LJ; Marks LD
  • Nat Commun 2015[]; 6 (ä): ä PMID26082275show ga
  • Unique determination of the atomic structure of technologically relevant surfaces is often limited by both a need for homogeneous crystals and ambiguity of registration between the surface and bulk. Atomically resolved secondary-electron imaging is extremely sensitive to this registration and is compatible with faceted nanomaterials, but has not been previously utilized for surface structure determination. Here we report a detailed experimental atomic-resolution secondary-electron microscopy analysis of the c(6 × 2) reconstruction on strontium titanate (001) coupled with careful simulation of secondary-electron images, density functional theory calculations and surface monolayer-sensitive aberration-corrected plan-view high-resolution transmission electron microscopy. Our work reveals several unexpected findings, including an amended registry of the surface on the bulk and strontium atoms with unusual seven-fold coordination within a typically high surface coverage of square pyramidal TiO5 units. Dielectric screening is found to play a critical role in attenuating secondary-electron generation processes from valence orbitals.
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