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10.1038/srep13536

http://scihub22266oqcxt.onion/10.1038/srep13536
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C4557037!4557037!26329479
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suck abstract from ncbi


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pmid26329479      Sci+Rep 2015 ; 5 (ä): ä
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  • The generalized Shockley-Queisser limit for nanostructured solar cells #MMPMID26329479
  • Xu Y; Gong T; Munday JN
  • Sci Rep 2015[]; 5 (ä): ä PMID26329479show ga
  • The Shockley-Queisser limit describes the maximum solar energy conversion efficiency achievable for a particular material and is the standard by which new photovoltaic technologies are compared. This limit is based on the principle of detailed balance, which equates the photon flux into a device to the particle flux (photons or electrons) out of that device. Nanostructured solar cells represent a novel class of photovoltaic devices, and questions have been raised about whether or not they can exceed the Shockley-Queisser limit. Here we show that single-junction nanostructured solar cells have a theoretical maximum efficiency of ?42% under AM 1.5 solar illumination. While this exceeds the efficiency of a non-concentrating planar device, it does not exceed the Shockley-Queisser limit for a planar device with optical concentration. We consider the effect of diffuse illumination and find that with optical concentration from the nanostructures of only?×?1,000, an efficiency of 35.5% is achievable even with 25% diffuse illumination. We conclude that nanostructured solar cells offer an important route towards higher efficiency photovoltaic devices through a built-in optical concentration.
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