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10.1002/anie.201502979

http://scihub22266oqcxt.onion/10.1002/anie.201502979
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C4515085!4515085!26037542
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suck abstract from ncbi


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pmid26037542      Angew+Chem+Int+Ed+Engl 2015 ; 54 (27): 7971-5
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  • Enhanced Raman Scattering from Vibro-Polariton Hybrid States** #MMPMID26037542
  • Shalabney A; George J; Hiura H; Hutchison JA; Genet C; Hellwig P; Ebbesen TW
  • Angew Chem Int Ed Engl 2015[Jun]; 54 (27): 7971-5 PMID26037542show ga
  • Ground-state molecular vibrations can be hybridized through strong coupling with the vacuum field of a cavity optical mode in the infrared region, leading to the formation of two new coherent vibro-polariton states. The spontaneous Raman scattering from such hybridized light?matter states was studied, showing that the collective Rabi splitting occurs at the level of a single selected bond. Moreover, the coherent nature of the vibro-polariton states boosts the Raman scattering cross-section by two to three orders of magnitude, revealing a new enhancement mechanism as a result of vibrational strong coupling. This observation has fundamental consequences for the understanding of light-molecule strong coupling and for molecular science.
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