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10.1186/1556-276X-9-679

http://scihub22266oqcxt.onion/10.1186/1556-276X-9-679
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C4493846!4493846!26088979
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suck abstract from ncbi


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pmid26088979      Nanoscale+Res+Lett 2014 ; 9 (ä): ä
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  • Galvanic synthesis of three-dimensional and hollow metallic nanostructures #MMPMID26088979
  • Park SH; Son JG; Lee TG; Kim J; Han SY; Park HM; Song JY
  • Nanoscale Res Lett 2014[]; 9 (ä): ä PMID26088979show ga
  • We report a low-cost, facile, and template-free electrochemical method of synthesizing three-dimensional (3D) hollow metallic nanostructures. The 3D nanoporous gold (3D-NPG) nanostructures were synthesized by a galvanic replacement reaction (GRR) using the different reduction potentials of silver and gold; hemispherical silver nanoislands were electrochemically deposited on cathodic substrates by a reverse-pulse potentiodynamic method without templates and then nanoporous gold layer replicated the shape of silver islands during the GRR process in an ultra-dilute electrolyte of gold(III) chloride trihydrate. Finally, the wet etching process of remaining silver resulted in the formation of 3D-NPG. During the GRR process, the application of bias voltage to the cathode decreased the porosity of 3D-NPG in the voltage range of 0.2 to -0.62 V. And the GRR process of silver nanoislands was also applicable to fabrication of the 3D hollow nanostructures of platinum and palladium. The 3D-NPG nanostructures were found to effectively enhance the SERS sensitivity of rhodamine 6G (R6G) molecules with a concentration up to 10-8 M.Electronic supplementary material: The online version of this article (doi:10.1186/1556-276X-9-679) contains supplementary material, which is available to authorized users.
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