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10.1038/srep10733

http://scihub22266oqcxt.onion/10.1038/srep10733
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suck abstract from ncbi


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pmid26035774
      Sci+Rep 2015 ; 5 (ä): 10733
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  • Advanced aqueous rechargeable lithium battery using nanoparticulate LiTi2(PO4)3/C as a superior anode #MMPMID26035774
  • Sun D ; Jiang Y ; Wang H ; Yao Y ; Xu G ; He K ; Liu S ; Tang Y ; Liu Y ; Huang X
  • Sci Rep 2015[Jun]; 5 (ä): 10733 PMID26035774 show ga
  • Poor cycling performance arising from the instability of anode is still a main challenge for aqueous rechargeable lithium batteries (ARLB). In the present work, a high performance LiTi2(PO4)3/C composite has been achieved by a novel and facile preparation method associated with an in-situ carbon coating approach. The LiTi2(PO4)3/C nanoparticles show high purity and the carbon layer is very uniform. When used as an anode material, the ARLB of LiTi2(PO4)3/C//LiMn2O4 delivered superior cycling stability with a capacity retention of 90% after 300 cycles at 30 mA g(-1) and 84% at 150 mA g(-1) over 1300 cycles. It also demonstrated excellent rate capability with reversible discharge capacities of 115 and 89 mAh g(-1) (based on the mass of anode) at 15 and 1500 mA g(-1), respectively. The superior electrochemical properties should be mainly ascribed to the high performance of LiTi2(PO4)3/C anode, benefiting from its nanostructure, high-quality carbon coating, appropriate crystal structure and excellent electrode surface stability as verified by Raman spectra, electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements.
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