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10.1038/srep10619 http://scihub22266oqcxt.onion/10.1038/srep10619 C4448549!4448549!26024339     free     free     free       Sci+Rep 2015 ; 5 (ä): ä Nephropedia Template TP {{tp|p=26024339|t=2015. Properties of Water Confined in Ionic Liquids |pdf=|usr=}}{{26024339}} gab.com Text Properties of Water Confined in Ionic Liquids JO: Sci Rep http://www.kidney.de/pget.php?&tw=1&pmid=26024339 #FOAvip The varying states of water confined in the nano-domain structures of typical room temperature ionic liquids (ILs) were investigated by 1H NMR and by measurements of self-diffusion coefficients while systematically varying the IL cations and anions. The NMR peaks for water in BF4-based ILs were clearly split, indicating the presence of two discrete states of confined water (H2O and HOD). Proton and/or deuterium exchange rate among the water molecules was very slowly in the water-pocket. Notably, no significant changes were observed in the chemical shifts of the ILs. Self-diffusion coefficient results showed that water molecules exhibit a similar degree of mobility, although their diffusion rate is one order of magnitude faster than that of the IL cations and anions. These findings provide information on a completely new type of confinement, that of liquid water in soft matter. Twit Text FOAVip Properties of Water Confined in Ionic Liquids ????Sci Rep http://www.kidney.de/pget.php?&tw=1&pmid=26024339 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=26024339 #FOAvip English Wikipedia <ref>{{Cite pmid|26024339}}</ref> Properties of Water Confined in Ionic Liquids #MMPMID26024339 Saihara K; Yoshimura Y; Ohta S; Shimizu A Sci Rep 2015[]; 5 (ä): ä PMID26024339show ga The varying states of water confined in the nano-domain structures of typical room temperature ionic liquids (ILs) were investigated by 1H NMR and by measurements of self-diffusion coefficients while systematically varying the IL cations and anions. The NMR peaks for water in BF4-based ILs were clearly split, indicating the presence of two discrete states of confined water (H2O and HOD). Proton and/or deuterium exchange rate among the water molecules was very slowly in the water-pocket. Notably, no significant changes were observed in the chemical shifts of the ILs. Self-diffusion coefficient results showed that water molecules exhibit a similar degree of mobility, although their diffusion rate is one order of magnitude faster than that of the IL cations and anions. These findings provide information on a completely new type of confinement, that of liquid water in soft matter. äProperties of Water Confined in Ionic Liquids (epmc).pdf DeepDyve Pubget Overpricing