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10.1002/anie.201405796

http://scihub22266oqcxt.onion/10.1002/anie.201405796
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C4214138!4214138!25196481
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suck abstract from ncbi

pmid25196481      Angew+Chem+Int+Ed+Engl 2014 ; 53 (43): 11498-500
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  • Anion Complexation and The Hofmeister Effect** #MMPMID25196481
  • Carnegie R; Gibb CLD; Gibb BC
  • Angew Chem Int Ed Engl 2014[Oct]; 53 (43): 11498-500 PMID25196481show ga
  • The 1H NMR spectroscopic analysis of the binding of ClO4? anion to the hydrophobic, concave binding site of a deep-cavity cavitand is presented. The strength of association between the host and ClO4? is controlled by both the nature and concentration of co-salts in a manner that follows the Hofmeister series. A model that partitions this trend into competitive binding of the co-salt anion to the hydrophobic pocket of the host, and counter-ion binding to its external carboxylates, successfully accounts for the observed changes in ClO4? affinity.
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