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10.1021/ja5046296

http://scihub22266oqcxt.onion/10.1021/ja5046296
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C4073881!4073881!24926794
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suck abstract from ncbi


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pmid24926794      J+Am+Chem+Soc 2014 ; 136 (25): 8915-8
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  • Lewis Base Catalyzed, Enantioselective, Intramolecular Sulfenoamination of Olefins #MMPMID24926794
  • Denmark SE; Chi HM
  • J Am Chem Soc 2014[Jun]; 136 (25): 8915-8 PMID24926794show ga
  • A method for the enantioselective, intramolecular sulfenoamination of various olefins has been developed using a chiral BINAM-based selenophosphoramide, Lewis base catalyst. Terminal and trans disubstituted alkenes afforded pyrrolidines, piperidines, and azepanes in high yields and high enantiomeric ratios via enantioselective formation and subsequent stereospecific capture of the thiiranium intermediate with the pendant tosyl-protected amine.
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