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10.1007/s00775-014-1109-6 http://scihub22266oqcxt.onion/10.1007/s00775-014-1109-6 C4031275!4031275 !24515615     free     free     free Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 211.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 245.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 245.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\24515615 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       J+Biol+Inorg+Chem 2014 ; 19 (4-5 ): 667-74 Nephropedia Template TP {{tp|p=24515615 |t=2014. Reinterpretation of the vibrational spectroscopy of the medicinal bioinorganic synthon c,c,t- Pt(NH3)2Cl2(OH)2 |pdf=|usr=}}{{24515615 }} gab.com Text Reinterpretation of the vibrational spectroscopy of the medicinal bioinorganic synthon c,c,t- Pt(NH3)2Cl2(OH)2 JO: J Biol Inorg Chem http://www.kidney.de/pget.php?&tw=1&pmid=24515615 #FOAvip The Pt(IV) complex c,c,t-[Pt(NH3)2Cl2(OH)2] is an important intermediate in the synthesis of Pt(IV) anticancer prodrugs and has been investigated as an anticancer agent in its own right. An analysis of the vibrational spectroscopy of this molecule was previously reported (Faggiani et al., Can. J. Chem. 60:529, 1982), in which crystallographic determination of the structure of the complex permitted a site group approach. The space group, however, was incorrectly assigned. In the present study we have redetermined at high resolution crystal structures of c,c,t-[Pt(NH3)2Cl2(OH)2] and c,c,t-[Pt(NH3)2Cl2(OH)2]·H2O2, which makes possible discussion of the effect of hydrogen bonding on the N-H and O-H vibrational bands. The correct crystallographic site symmetry of the platinum complex in the c,c,t-[Pt(NH3)2Cl2(OH)2] structure is used to conduct a new vibrational analysis using both group-theoretical and modern density functional theory methods. This analysis reveals the nature and symmetry of the "missing band" described in the original publication and suggests a possible explanation for its disappearance. Twit Text FOAVip Reinterpretation of the vibrational spectroscopy of the medicinal bioinorganic synthon c,c,t- Pt(NH3)2Cl2(OH)2 ????J Biol Inorg Chem http://www.kidney.de/pget.php?&tw=1&pmid=24515615 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=24515615 #FOAvip English Wikipedia <ref>{{Cite pmid|24515615 }}</ref> Reinterpretation of the vibrational spectroscopy of the medicinal bioinorganic synthon c,c,t- Pt(NH3)2Cl2(OH)2 #MMPMID24515615 Johnstone TC ; Lippard SJ J Biol Inorg Chem 2014[Jun]; 19 (4-5 ): 667-74 PMID24515615 show ga The Pt(IV) complex c,c,t-[Pt(NH3)2Cl2(OH)2] is an important intermediate in the synthesis of Pt(IV) anticancer prodrugs and has been investigated as an anticancer agent in its own right. An analysis of the vibrational spectroscopy of this molecule was previously reported (Faggiani et al., Can. J. Chem. 60:529, 1982), in which crystallographic determination of the structure of the complex permitted a site group approach. The space group, however, was incorrectly assigned. In the present study we have redetermined at high resolution crystal structures of c,c,t-[Pt(NH3)2Cl2(OH)2] and c,c,t-[Pt(NH3)2Cl2(OH)2]·H2O2, which makes possible discussion of the effect of hydrogen bonding on the N-H and O-H vibrational bands. The correct crystallographic site symmetry of the platinum complex in the c,c,t-[Pt(NH3)2Cl2(OH)2] structure is used to conduct a new vibrational analysis using both group-theoretical and modern density functional theory methods. This analysis reveals the nature and symmetry of the "missing band" described in the original publication and suggests a possible explanation for its disappearance. |Cisplatin/analogs & derivatives/chemistry [MESH] |Crystallography [MESH] |Platinum/chemistry [MESH]Reinterpretation of the vibrational spectroscopy of the medicinal bioi(epmc).pdf DeepDyve Pubget Overpricing