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10.1039/d5ra07326j

http://scihub22266oqcxt.onion/10.1039/d5ra07326j
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C12693423!12693423 !41384073
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suck abstract from ncbi

pmid41384073
      RSC+Adv 2025 ; 15 (57 ): 49088-49093
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  • Electrochemical preparation of bismuthene quantum dots for the selective electroreduction of O(2) to peroxide #MMPMID41384073
  • Isaac BR ; Mohapatra S ; Alwarappan S ; Pillai VK
  • RSC Adv 2025[Dec]; 15 (57 ): 49088-49093 PMID41384073 show ga
  • Bismuthene quantum dots (BiQDs), as a zero-dimensional (0D) material, offer significant potential in electrocatalysis due to their quantum confinement, edge effects, and unique electronic structure. Herein, we report a facile electrochemical exfoliation strategy for the synthesis of crystalline BiQDs (lateral dimensions of 2.2 nm) in N-methylpyrrolidone (NMP) at room temperature. Their electrocatalytic activity towards the oxygen reduction reaction (ORR) in alkaline media is systematically evaluated. The observed Tafel slope of approximately 40 mV dec(-1) and the high exchange current density (6.0 × 10(-8) A cm(-2)) indicate notable kinetic improvements over conventional Pt-based electrocatalysts and enhanced cycling stability. BiQDs exhibit enhanced ORR performance following a two-electron transfer mechanism. This work highlights the promising role of BiQDs as efficient and environmentally friendly ORR electrocatalysts.
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