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10.1039/d5ra07909h http://scihub22266oqcxt.onion/10.1039/d5ra07909h C12691338!12691338 !41384056     free     free     free       RSC+Adv 2025 ; 15 (57 ): 49159-49164 Nephropedia Template TP {{tp|p=41384056 |t=2025. MOF MIL-53(Al) catalyzed hydroacylation of azodicarboxylates: sustainable catalyst for heterogeneous acylhydrazide synthesis |pdf=|usr=}}{{41384056 }} gab.com Text MOF MIL-53(Al) catalyzed hydroacylation of azodicarboxylates: sustainable catalyst for heterogeneous acylhydrazide synthesis JO: RSC Adv http://www.kidney.de/pget.php?&tw=1&pmid=41384056 #FOAvip This study reports one of the few examples of acylhydrazide synthesis catalyzed by the metal-organic framework (MOF) MIL-53(Al) via the aldehyde C(sp(2))-H hydrazidation reaction. The material exhibited high catalytic performance, displaying a broad substrate scope and affording yields of up to 97%. The catalyst retained its structural integrity and activity for at least four consecutive cycles, with no significant metal leaching. Notably, MIL-53(Al) was synthesized from waste-derived materials and thoroughly characterized to confirm its crystallinity, structural integrity, and porosity - features essential to its catalytic function. This work demonstrates the potential of upcycled MIL-53(Al) as a stable, sustainable, and low-cost heterogeneous catalyst for the synthesis of valuable acylhydrazides, offering an attractive alternative to conventional systems that rely on toxic metal promoters. Twit Text FOAVip MOF MIL-53(Al) catalyzed hydroacylation of azodicarboxylates: sustainable catalyst for heterogeneous acylhydrazide synthesis ????RSC Adv http://www.kidney.de/pget.php?&tw=1&pmid=41384056 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=41384056 #FOAvip English Wikipedia <ref>{{Cite pmid|41384056 }}</ref> MOF MIL-53(Al) catalyzed hydroacylation of azodicarboxylates: sustainable catalyst for heterogeneous acylhydrazide synthesis #MMPMID41384056 Báez R ; Marchini L ; Delgado JAC ; San Martín S ; Verdugo F ; Araújo KC ; Pereira EC ; Varma RS ; Paixão MW ; Jiménez CA RSC Adv 2025[Dec]; 15 (57 ): 49159-49164 PMID41384056 show ga This study reports one of the few examples of acylhydrazide synthesis catalyzed by the metal-organic framework (MOF) MIL-53(Al) via the aldehyde C(sp(2))-H hydrazidation reaction. The material exhibited high catalytic performance, displaying a broad substrate scope and affording yields of up to 97%. The catalyst retained its structural integrity and activity for at least four consecutive cycles, with no significant metal leaching. Notably, MIL-53(Al) was synthesized from waste-derived materials and thoroughly characterized to confirm its crystallinity, structural integrity, and porosity - features essential to its catalytic function. This work demonstrates the potential of upcycled MIL-53(Al) as a stable, sustainable, and low-cost heterogeneous catalyst for the synthesis of valuable acylhydrazides, offering an attractive alternative to conventional systems that rely on toxic metal promoters. ?MOF MIL-53(Al) catalyzed hydroacylation of azodicarboxylates: sustaina(epmc).pdf DeepDyve Pubget Overpricing