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10.1038/s41467-025-64208-1

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suck abstract from ncbi


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pmid41102144
      Nat+Commun 2025 ; 16 (1 ): 9179
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  • High-temperature oxide ceramic microwave absorber enabled by thermionic migration mediated by electron delocalization #MMPMID41102144
  • Cui R ; Duan Z ; Li Y ; Zhang X ; Liu X ; Yang G ; Yang L ; Zhao B ; Wan C
  • Nat Commun 2025[Oct]; 16 (1 ): 9179 PMID41102144 show ga
  • The escalating demand for long-term high-temperature microwave-absorbing materials (HTMAMs) in high-speed aerospace stealth is hindered by limitations such as magnetic loss degradation or oxidation risks. Herein, we introduce rare earth zirconate ceramics that exhibit air stability up to 1600?°C. Abundant oxygen vacancies significantly enhance permittivity and thus microwave-absorbing performance through activated thermionic migration at elevated temperatures. Moreover, the thermionic-facilitated permittivity can be meticulously modulated by electron delocalization, with the extent governed by lattice disorder. We demonstrate this concept through a dual-layer Er(2)Zr(2)O(7)/Gd(2)Zr(2)O(7) structure to further optimize impedance matching, achieving an ultra-wide bandwidth (8.27?GHz) and strong absorption (-64.61?dB) at ultrathin thicknesses under 1.2?mm at 600?°C mainly by macroscopic interfacial resonance, alongside an ultralow thermal conductivity (1.61?W?m(-1)?K(-1)). This work presents an innovative approach to design high-performance and anti-oxidative HTMAMs through thermionic migration tuned by electron delocalization, advancing structural-functional integrated materials for extreme environments.
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