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10.1002/cssc.202501540 http://scihub22266oqcxt.onion/10.1002/cssc.202501540 41391181!?!41391181 Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=41391181&cmd=llinks): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 215       ChemSusChem 2025 ; ? (?): e202501540 Nephropedia Template TP {{tp|p=41391181|t=2025. Merging Lignin and Glycerol Carbonate Valorization Toward the Green Synthesis of beta-Adrenergic Blocker Esmolol |pdf=|usr=}}{{41391181}} gab.com Text Merging Lignin and Glycerol Carbonate Valorization Toward the Green Synthesis of beta-Adrenergic Blocker Esmolol JO: ChemSusChem http://www.kidney.de/pget.php?&tw=1&pmid=41391181 #FOAvip Producing nitrogen-containing chemicals through the direct combination of by-products readily available from agricultural waste, including renewable aromatic building blocks from lignin, is a highly attractive approach for sustainable biorefining processes. Here, we describe a novel synthetic/catalytic route toward the production of the highly valuable beta-adrenergic blocker esmolol. Our strategy consists of: 1) Reductive Catalytic Fractionation (RCF) of sugarcane lignocellulose mediated by copper porous metal oxides (Cu(20)PMO) in MeOH, leading to the in situ formation of methyl 3-(4-hydroxyphenyl) propionate (1H) with good selectivity (>70%), followed by 2) the selective catalytic amination of glycerol carbonate (GlyC) with isopropyl amine via the borrowing hydrogen strategy, and 3) the subsequent utilization of the obtained amine intermediate as a phenol alkylating agent in combination with 1H to afford the desired beta-adrenergic blocker esmolol (1Ha). Twit Text FOAVip Merging Lignin and Glycerol Carbonate Valorization Toward the Green Synthesis of beta-Adrenergic Blocker Esmolol ????ChemSusChem http://www.kidney.de/pget.php?&tw=1&pmid=41391181 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=41391181 #FOAvip English Wikipedia <ref>{{Cite pmid|41391181}}</ref> Merging Lignin and Glycerol Carbonate Valorization Toward the Green Synthesis of beta-Adrenergic Blocker Esmolol #MMPMID41391181 Castillo-Garcia AA; Barta K ChemSusChem 2025[Dec]; ? (?): e202501540 PMID41391181show ga Producing nitrogen-containing chemicals through the direct combination of by-products readily available from agricultural waste, including renewable aromatic building blocks from lignin, is a highly attractive approach for sustainable biorefining processes. Here, we describe a novel synthetic/catalytic route toward the production of the highly valuable beta-adrenergic blocker esmolol. Our strategy consists of: 1) Reductive Catalytic Fractionation (RCF) of sugarcane lignocellulose mediated by copper porous metal oxides (Cu(20)PMO) in MeOH, leading to the in situ formation of methyl 3-(4-hydroxyphenyl) propionate (1H) with good selectivity (>70%), followed by 2) the selective catalytic amination of glycerol carbonate (GlyC) with isopropyl amine via the borrowing hydrogen strategy, and 3) the subsequent utilization of the obtained amine intermediate as a phenol alkylating agent in combination with 1H to afford the desired beta-adrenergic blocker esmolol (1Ha). ?Merging Lignin and Glycerol Carbonate Valorization Toward the Green Sy(epmc).pdf DeepDyve Pubget Overpricing