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10.1021/acs.joc.5c01768 http://scihub22266oqcxt.onion/10.1021/acs.joc.5c01768 41388980!?!41388980       J+Org+Chem 2025 ; ? (?): ? Nephropedia Template TP {{tp|p=41388980|t=2025. Weakly Coordinating Amide-Directed C-H Activation/Annulation with Ru(II) Catalyst for the Construction of 3-(Trifluoromethyl)isoquinolinones from Benzamides |pdf=|usr=}}{{41388980}} gab.com Text Weakly Coordinating Amide-Directed C-H Activation/Annulation with Ru(II) Catalyst for the Construction of 3-(Trifluoromethyl)isoquinolinones from Benzamides JO: J Org Chem http://www.kidney.de/pget.php?&tw=1&pmid=41388980 #FOAvip The novel strategy utilizing ruthenium-catalyzed intermolecular cyclization of benzamides with trifluoromethylated iminosulfonium ylides to synthesize N-H-unsubstituted 3-(trifluoromethyl)isoquinolinone derivatives was developed. (15)N-labeling experiments confirmed that the nitrogen atom in the product originates from the benzamide substrates, which varies from previous mechanisms, where trifluoromethyl iminosulfonium ylides serve as nitrogen donors. The present work establishes a practical route for the preparation of N-H-unsubstituted 3-(trifluoromethyl)isoquinolinone derivatives, successfully addressing the challenges of cumbersome synthetic procedures and low yields in conventional approaches. Twit Text FOAVip Weakly Coordinating Amide-Directed C-H Activation/Annulation with Ru(II) Catalyst for the Construction of 3-(Trifluoromethyl)isoquinolinones from Benzamides ????J Org Chem http://www.kidney.de/pget.php?&tw=1&pmid=41388980 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=41388980 #FOAvip English Wikipedia <ref>{{Cite pmid|41388980}}</ref> Weakly Coordinating Amide-Directed C-H Activation/Annulation with Ru(II) Catalyst for the Construction of 3-(Trifluoromethyl)isoquinolinones from Benzamides #MMPMID41388980 Li Y; Huang X; Cai C J Org Chem 2025[Dec]; ? (?): ? PMID41388980show ga The novel strategy utilizing ruthenium-catalyzed intermolecular cyclization of benzamides with trifluoromethylated iminosulfonium ylides to synthesize N-H-unsubstituted 3-(trifluoromethyl)isoquinolinone derivatives was developed. (15)N-labeling experiments confirmed that the nitrogen atom in the product originates from the benzamide substrates, which varies from previous mechanisms, where trifluoromethyl iminosulfonium ylides serve as nitrogen donors. The present work establishes a practical route for the preparation of N-H-unsubstituted 3-(trifluoromethyl)isoquinolinone derivatives, successfully addressing the challenges of cumbersome synthetic procedures and low yields in conventional approaches. ?Weakly Coordinating Amide-Directed C-H Activation/Annulation with Ru(I(epmc).pdf DeepDyve Pubget Overpricing