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10.1021/acsami.5c17688 http://scihub22266oqcxt.onion/10.1021/acsami.5c17688 41359357!?!41359357 Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=41359357&cmd=llinks): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 215       ACS+Appl+Mater+Interfaces 2025 ; ? (?): ? Nephropedia Template TP {{tp|p=41359357|t=2025. NO(3)(-)-Mediated Solvent Immobilization in Medium-Concentration Ether-Based Electrolytes: Enabling High-Voltage Lithium Metal Batteries with Wide Temperature Ranges |pdf=|usr=}}{{41359357}} gab.com Text NO(3)(-)-Mediated Solvent Immobilization in Medium-Concentration Ether-Based Electrolytes: Enabling High-Voltage Lithium Metal Batteries with Wide Temperature Ranges JO: ACS Appl Mater Interfaces http://www.kidney.de/pget.php?&tw=1&pmid=41359357 #FOAvip Ether-based electrolytes have been regarded as promising candidates for high-energy-density lithium metal batteries, yet they face significant challenges in maintaining stable cycling under high voltage (>4.3 V) and adapting to extreme environmental conditions. This study proposes an innovative solvent immobilization strategy to enhance the oxidative stability of ether electrolytes and stabilize interfaces with both lithium metal anodes and high-voltage cathodes. A unique "bead string" structure was formed by self-assembly of nitrate anion (NO(3)(-)) and long-chain ether solvent, effectively immobilizing solvent molecules in the bulk electrolyte. This structure facilitates the formation of an anion-rich electric double layer (EDL) at a medium electrolyte concentration (1.5 M), leading to the formation of a highly stable, inorganic-dominated passivation layer on the surfaces of both the lithium metal anode and high-voltage cathodes. The optimized electrolyte enables Li || LiCoO(2) and Li || NCM811 batteries to achieve exceptional cycling stability (81.8% capacity retention after 1400 cycles at 4.3 V and 73.4% capacity retention after 600 cycles at 4.45 V for Li || LiCoO(2); 79.8% capacity retention after 1500 cycles at 4.3 V for Li || NCM811). Moreover, the battery can operate across an ultrawide temperature range of -60 to 70 degrees C. Twit Text FOAVip NO(3)(-)-Mediated Solvent Immobilization in Medium-Concentration Ether-Based Electrolytes: Enabling High-Voltage Lithium Metal Batteries with Wide Temperature Ranges ????ACS Appl Mater Interfaces http://www.kidney.de/pget.php?&tw=1&pmid=41359357 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=41359357 #FOAvip English Wikipedia <ref>{{Cite pmid|41359357}}</ref> NO(3)(-)-Mediated Solvent Immobilization in Medium-Concentration Ether-Based Electrolytes: Enabling High-Voltage Lithium Metal Batteries with Wide Temperature Ranges #MMPMID41359357 Xiong J; Shi J; Zheng T; Zheng M; Huang H; Wang S; Liu Z; Xu Z; Shen L; Xia Y ACS Appl Mater Interfaces 2025[Dec]; ? (?): ? PMID41359357show ga Ether-based electrolytes have been regarded as promising candidates for high-energy-density lithium metal batteries, yet they face significant challenges in maintaining stable cycling under high voltage (>4.3 V) and adapting to extreme environmental conditions. This study proposes an innovative solvent immobilization strategy to enhance the oxidative stability of ether electrolytes and stabilize interfaces with both lithium metal anodes and high-voltage cathodes. A unique "bead string" structure was formed by self-assembly of nitrate anion (NO(3)(-)) and long-chain ether solvent, effectively immobilizing solvent molecules in the bulk electrolyte. This structure facilitates the formation of an anion-rich electric double layer (EDL) at a medium electrolyte concentration (1.5 M), leading to the formation of a highly stable, inorganic-dominated passivation layer on the surfaces of both the lithium metal anode and high-voltage cathodes. The optimized electrolyte enables Li || LiCoO(2) and Li || NCM811 batteries to achieve exceptional cycling stability (81.8% capacity retention after 1400 cycles at 4.3 V and 73.4% capacity retention after 600 cycles at 4.45 V for Li || LiCoO(2); 79.8% capacity retention after 1500 cycles at 4.3 V for Li || NCM811). Moreover, the battery can operate across an ultrawide temperature range of -60 to 70 degrees C. ?NO(3)(-)-Mediated Solvent Immobilization in Medium-Concentration Ether(epmc).pdf DeepDyve Pubget Overpricing