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10.1002/smtd.202502192 http://scihub22266oqcxt.onion/10.1002/smtd.202502192 41351210!?!41351210 Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=41351210&cmd=llinks): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 215       Small+Methods 2025 ; ? (?): e02192 Nephropedia Template TP {{tp|p=41351210|t=2025. MOF-Derived Entropy-Stabilized Quinary Alloy@Cellulose Aerogel for Ultrafast Tetracycline Degradation via PMS Activation |pdf=|usr=}}{{41351210}} gab.com Text MOF-Derived Entropy-Stabilized Quinary Alloy@Cellulose Aerogel for Ultrafast Tetracycline Degradation via PMS Activation JO: Small Methods http://www.kidney.de/pget.php?&tw=1&pmid=41351210 #FOAvip The persistent contamination of aquatic ecosystems by recalcitrant tetracycline antibiotics demands advanced catalytic systems beyond conventional oxidation methods. Here, a sustainable high-entropy catalyst, FeMnCoZnCu@NCNP@CA is reported, comprising MOF-derived multi-metallic nanoparticles confined within a nitrogen-doped carbon matrix and anchored on a 3D cellulose aerogel scaffold. The hybrid is obtained by pyrolyzing a quinary FeMnCoZnCu-NTA MOF precursor. This hierarchical design integrates several key features: high-entropy stabilization to suppress phase segregation, N-doping-driven charge redistribution to enhance conductivity and active-site density and multivalent redox coupling to promote reactive oxygen species generation (SO(4)*(-), *OH, (1)O(2)) and accelerate electron transfer. The confined carbon matrix effectively minimizes metal leaching (<0.1 ppm), while the aerogel macroporosity ensures rapid diffusion and enables >85% catalyst recovery. Under optimal conditions ([Catalyst] = 0.25 g L(-) (1), [PMS] = 0.31 g L(-) (1), pH = 3), FeMnCoZnCu@NCNP@CA achieves >98% tetracycline degradation within 15 min, exhibiting a rate constant (k = 0.070 +/- 0.013 min(-) (1)) that is 4.2 times higher than the mono-metallic Fe@NCNP and surpasses di-, tri- and tetra-metallic analogues. This work highlights MOF-derived high-entropy hybrids as a promising platform for antibiotic remediation through the synergistic integration of multi-metallic entropy, nitrogen doping, structural confinement and biomass aerogel engineering. Twit Text FOAVip MOF-Derived Entropy-Stabilized Quinary Alloy@Cellulose Aerogel for Ultrafast Tetracycline Degradation via PMS Activation ????Small Methods http://www.kidney.de/pget.php?&tw=1&pmid=41351210 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=41351210 #FOAvip English Wikipedia <ref>{{Cite pmid|41351210}}</ref> MOF-Derived Entropy-Stabilized Quinary Alloy@Cellulose Aerogel for Ultrafast Tetracycline Degradation via PMS Activation #MMPMID41351210 Erum JKE; Alshahrani T; Yang X; Gao J Small Methods 2025[Dec]; ? (?): e02192 PMID41351210show ga The persistent contamination of aquatic ecosystems by recalcitrant tetracycline antibiotics demands advanced catalytic systems beyond conventional oxidation methods. Here, a sustainable high-entropy catalyst, FeMnCoZnCu@NCNP@CA is reported, comprising MOF-derived multi-metallic nanoparticles confined within a nitrogen-doped carbon matrix and anchored on a 3D cellulose aerogel scaffold. The hybrid is obtained by pyrolyzing a quinary FeMnCoZnCu-NTA MOF precursor. This hierarchical design integrates several key features: high-entropy stabilization to suppress phase segregation, N-doping-driven charge redistribution to enhance conductivity and active-site density and multivalent redox coupling to promote reactive oxygen species generation (SO(4)*(-), *OH, (1)O(2)) and accelerate electron transfer. The confined carbon matrix effectively minimizes metal leaching (<0.1 ppm), while the aerogel macroporosity ensures rapid diffusion and enables >85% catalyst recovery. Under optimal conditions ([Catalyst] = 0.25 g L(-) (1), [PMS] = 0.31 g L(-) (1), pH = 3), FeMnCoZnCu@NCNP@CA achieves >98% tetracycline degradation within 15 min, exhibiting a rate constant (k = 0.070 +/- 0.013 min(-) (1)) that is 4.2 times higher than the mono-metallic Fe@NCNP and surpasses di-, tri- and tetra-metallic analogues. This work highlights MOF-derived high-entropy hybrids as a promising platform for antibiotic remediation through the synergistic integration of multi-metallic entropy, nitrogen doping, structural confinement and biomass aerogel engineering. ?MOF-Derived Entropy-Stabilized Quinary Alloy@Cellulose Aerogel for Ult(epmc).pdf DeepDyve Pubget Overpricing