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10.1039/d5cp03622d

http://scihub22266oqcxt.onion/10.1039/d5cp03622d
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41347443!?!41347443

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suck abstract from ncbi

pmid41347443      Phys+Chem+Chem+Phys 2025 ; ? (?): ?
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  • Multicycle operando Raman spectroscopy reveals reversible and irreversible transitions in LiNiO(2) electrodes #MMPMID41347443
  • Del Campo Ortiz E; Neale AR; Sonni M; Daniels LM; Zukowska GZ; Rosseinsky MJ; Marcinek M; Hardwick LJ
  • Phys Chem Chem Phys 2025[Dec]; ? (?): ? PMID41347443show ga
  • Operando Raman spectroscopy of the delithiation and lithiation of LiNiO(2) positive electrodes is reported over the first three cycles. Optimisation of the operando electrochemical Raman cell configuration facilitated the characterisation of composite electrodes across multiple cycles with high relevance for practical Li-ion cell chemistry. Tracking the E(g) and A(1g) Raman modes highlighted localised irreversible changes, particularly correlated to first-cycle inefficiencies in LiNiO(2), followed by reversible band shifts and intensity changes upon subsequent cycles. Furthermore, trends in both the band position and intensities were related to the state of lithiation (x(Li) in Li(x)NiO(2)) and the phase transitions through hexagonal and monoclinic phases (H1, M, H2 and H3).
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