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Metal atom chemistry as a direct pathway to access homoleptic mono- and dinuclear isonitrile compounds of the iron triad Fe, Co, and Ni #MMPMID40642794
Emmert JM; Rust J; Lehmann CW; Schneider JJ
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The co-condensation of atomic metal vapors of iron, nickel and cobalt with toluene, followed by a direct reaction with isonitriles, between -30 degrees C and -78 degrees C, yields stable homoleptic metal isonitrile complexes. Complexes of Fe, Ni, and Co with DippNC (Dipp = 2,6-(CH(CH(3))(2))(2)C(6)H(3)) and 4-fluorophenylisonitrile (4-FPI) are obtained in high yields using this method. This method offers an efficient and straightforward approach compared to previously reported syntheses.