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10.1016/j.jhazmat.2020.123472

http://scihub22266oqcxt.onion/10.1016/j.jhazmat.2020.123472
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suck abstract from ncbi


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pmid32731115      J+Hazard+Mater 2021 ; 402 (ä): 123472
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  • Pyrolysis dynamics of two medical plastic wastes: Drivers, behaviors, evolved gases, reaction mechanisms, and pathways #MMPMID32731115
  • Ding Z; Chen H; Liu J; Cai H; Evrendilek F; Buyukada M
  • J Hazard Mater 2021[Jan]; 402 (ä): 123472 PMID32731115show ga
  • The public has started to increasingly scrutinize the proper disposal and treatment of rapidly growing medical wastes, in particular, given the COVID-19 pandemic, raised awareness, and the advances in the health sector. This research aimed to characterize pyrolysis drivers, behaviors, products, reaction mechanisms, and pathways via TG-FTIR and Py-GC/MS analyses as a function of the two medical plastic wastes of syringes (SY) and medical bottles (MB), conversion degree, degradation stage, and the four heating rates (5,10, 20, and 40 degrees C/min). SY and MB pyrolysis ranged from 394.4 to 501 and from 417.9 to 517 degrees C, respectively. The average activation energy was 246.5 and 268.51 kJ/mol for the SY and MB devolatilization, respectively. MB appeared to exhibit a better pyrolysis performance with a higher degradation rate and less residues. The most suitable reaction mechanisms belonged to a geometrical contraction model (R(2)) for the SY pyrolysis and to a nucleation growth model (A(1.2)) for the MB pyrolysis. The main evolved gases were C(4)-C(24) alkenes and dienes for SY and C(6)-C(41) alkanes and C(8)-C(41) alkenes for MB. The pyrolysis dynamics and reaction pathways of the medical plastic wastes have important implications for waste stream reduction, pollution control, and reactor optimization.
  • |*Medical Waste[MESH]
  • |*Pyrolysis[MESH]
  • |COVID-19/epidemiology/virology[MESH]
  • |Gas Chromatography-Mass Spectrometry[MESH]
  • |Gases/*chemistry[MESH]
  • |Kinetics[MESH]
  • |Plastics/*chemistry[MESH]
  • |SARS-CoV-2/isolation & purification[MESH]
  • |Spectroscopy, Fourier Transform Infrared[MESH]
  • |Thermodynamics[MESH]


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