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Deprecated: Implicit conversion from float 245.2 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Biomass+Convers+Biorefin 2022 ; 12 (6): 2185-2202 Nephropedia Template TP
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Facile preparation of magnetic porous carbon monolith from waste corrugated cardboard box for solar steam generation and adsorption #MMPMID32395400
Ma Y; Cao J
Biomass Convers Biorefin 2022[]; 12 (6): 2185-2202 PMID32395400show ga
Porous carbon monoliths (PCMs) were prepared from waste corrugated cardboard box (WCCB) via slurrying in FeCl(3) solution followed by molding and thermal treatment. The thermal process was analyzed by a thermogravimetric analyzer coupled with a Fourier transform infrared spectrometer. The evolution of physicochemical characteristics of PCMs was studied. The photothermal conversion and solar steam generation performances of the optimal sample (PCM(Fe/600)) were evaluated. The adsorption properties of PCM(Fe/600) for methylene blue (MB) were investigated. Results showed that Fe(3+) promoted the breaking of cellulose chains in WCCB, leading to the occurrence of pyrolysis of WCCB at lower temperatures and the reduction of activation energy by 76.63 kJ mol(-1). Char yield raised because volatile radicals were captured by FeCl(3)-derived amorphous Fe(III) species, then involved in char formation. Amorphous Fe(III) continuously converted into Fe(3)O(4) crystallites with carbonization temperature increasing from 400 to 700 degrees C, then alpha-Fe was formed at 800 degrees C via the carbothermal reduction of Fe(3)O(4). FeCl(3) was favorable to the formation of a developed microporous structure. Surface area significantly increased with carbonization temperature increasing from 400 to 600 degrees C due to the removal of volatiles. The etching of carbon by Fe(3)O(4) above 700 degrees C also led to the increase of surface area. PCM(Fe/600) exhibited higher optical absorption than other samples due to its high graphite degree and porosity. It also had excellent photothermal performance; thus, solar steam yield was 1.46 times that of the pure water with the assistance of PCM(Fe/600). PCM(Fe/600) in floating state was effective in adsorption of MB from water. Besides, the adsorption behavior fitted Langmuir model with a monolayer adsorption capacity reached up to 70.9 mg g(-1).