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10.1021/acsomega.7b00259

http://scihub22266oqcxt.onion/10.1021/acsomega.7b00259
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31457533!6641066!31457533
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suck abstract from ncbi


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pmid31457533      ACS+Omega 2017 ; 2 (4): 1687-1695
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  • Low-Cost and High-Performance Hard Carbon Anode Materials for Sodium-Ion Batteries #MMPMID31457533
  • Wang K; Jin Y; Sun S; Huang Y; Peng J; Luo J; Zhang Q; Qiu Y; Fang C; Han J
  • ACS Omega 2017[Apr]; 2 (4): 1687-1695 PMID31457533show ga
  • As an anode material for sodium-ion batteries (SIBs), hard carbon (HC) presents high specific capacity and favorable cycling performance. However, high cost and low initial Coulombic efficiency (ICE) of HC seriously limit its future commercialization for SIBs. A typical biowaste, mangosteen shell was selected as a precursor to prepare low-cost and high-performance HC via a facile one-step carbonization method, and the influence of different heat treatments on the morphologies, microstructures, and electrochemical performances was investigated systematically. The microstructure evolution studied using X-ray diffraction, Raman, Brunauer-Emmett-Teller, and high-resolution transmission electron microscopy, along with electrochemical measurements, reveals the optimal carbonization condition of the mangosteen shell: HC carbonized at 1500 degrees C for 2 h delivers the highest reversible capacity of approximately 330 mA h g(-1) at a current density of 20 mA g(-1), a capacity retention of approximately 98% after 100 cycles, and an ICE of approximately 83%. Additionally, the sodium-ion storage behavior of HC is deeply analyzed using galvanostatic intermittent titration and cyclic voltammetry technologies.
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