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10.1107/S1600536812041645

http://scihub22266oqcxt.onion/10.1107/S1600536812041645
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23284336!3515109!23284336
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suck abstract from ncbi


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pmid23284336      Acta+Crystallogr+Sect+E+Struct+Rep+Online 2012 ; 68 (Pt 11): m1349-50
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  • Poly aqua-(mu(2)-pyrimidine-2-carboxyl-ato-kappa(4)O,N:O ,N )(nitrato-kappaO)cadmium #MMPMID23284336
  • In-Noi O; Chainok K; Harding DJ
  • Acta Crystallogr Sect E Struct Rep Online 2012[Nov]; 68 (Pt 11): m1349-50 PMID23284336show ga
  • In the title polymer, [Cd(C(5)H(3)N(2)O(2))(NO(3))(H(2)O)](n), the Cd(II) atom is seven-coordinate in a distorted capped octa-hedral geometry by two N atoms of two different pyrimidine dicarboxyl-ate (pmc) ligands, three O atoms from three separate pmc ligands, and two O atoms of disordered nitrate anions or water mol-ecules. The Cd(II) atoms are bridged by the pmc ligands in a chelating/bridging bis-bidentate and chelating bidentate mode, forming sheets parallel to (20-1). The sheets are further linked into a three-dimensional supra-molecular network via classical O-Hcdots, three dots, centeredO hydrogen bonds involving the nitrate anions and coordinating water mol-ecules. Intra-molecular O-Hcdots, three dots, centeredO hydrogen bonding is also observed. The non-coordinating nitrate O atoms are disordered over two sets of sites with occupancies of 0.57 (7) and 0.43 (7).
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