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10.1126/sciadv.aaq1293

http://scihub22266oqcxt.onion/10.1126/sciadv.aaq1293
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C5873843!5873843 !29600273
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suck abstract from ncbi


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pmid29600273
      Sci+Adv 2018 ; 4 (3 ): eaaq1293
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  • The photoreactive free radical in eumelanin #MMPMID29600273
  • Mostert AB ; Rienecker SB ; Noble C ; Hanson GR ; Meredith P
  • Sci Adv 2018[Mar]; 4 (3 ): eaaq1293 PMID29600273 show ga
  • Melanin is the primary photoprotecting pigment in humans as well as being implicated in the development of deadly melanoma. The material also conducts electricity and has thus become a bioelectronic model for proton-to-electron transduction. Central to these phenomena are its spin properties-notably two linked species derived from carbon-centered and semiquinone radicals. Using a novel in situ photoinduced electron paramagnetic resonance technique with simultaneous electrical measurements, we have elucidated for the first time the distinct photoreactivity of the two different radical species. We find that the production of the semiquinone is light- and water-driven, explaining the electrical properties and revealing biologically relevant photoreactivity.
  • |*Light [MESH]
  • |Electron Spin Resonance Spectroscopy [MESH]
  • |Free Radicals/*chemistry [MESH]
  • |Melanins/*chemistry [MESH]
  • |Time Factors [MESH]


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