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10.1098/rspa.2016.0859 http://scihub22266oqcxt.onion/10.1098/rspa.2016.0859 C5415689!5415689 !28484329     free     free     free Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\28484329 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       Proc+Math+Phys+Eng+Sci 2017 ; 473 (2200 ): 20160859 Nephropedia Template TP {{tp|p=28484329 |t=2017. Some aspects of radical cascade and relay reactions |pdf=|usr=}}{{28484329 }} gab.com Text Some aspects of radical cascade and relay reactions JO: Proc Math Phys Eng Sci http://www.kidney.de/pget.php?&tw=1&pmid=28484329 #FOAvip The ability to create carbon-carbon bonds is at the heart of organic synthesis. Radical processes are particularly apt at creating such bonds, especially in cascade or relay sequences where more than one bond is formed, allowing for a rapid assembly of complex structures. In the present brief overview, examples taken from the authors' laboratory will serve to illustrate the strategic impact of radical-based approaches on synthetic planning. Transformations involving nitrogen-centred radicals, electron transfer from metallic nickel and the reversible degenerative exchange of xanthates will be presented and discussed. The last method has proved to be a particularly powerful tool for the intermolecular creation of carbon-carbon bonds by radical additions even to unactivated alkenes. Various functional groups can be brought into the same molecule in a convergent manner and made to react together in order to further increase the structural complexity. One important benefit of this chemistry is the so-called RAFT/MADIX technology for the manufacture of block copolymers of almost any desired architecture. Twit Text FOAVip Some aspects of radical cascade and relay reactions ????Proc Math Phys Eng Sci http://www.kidney.de/pget.php?&tw=1&pmid=28484329 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=28484329 #FOAvip English Wikipedia <ref>{{Cite pmid|28484329 }}</ref> Some aspects of radical cascade and relay reactions #MMPMID28484329 Quiclet-Sire B ; Zard SZ Proc Math Phys Eng Sci 2017[Apr]; 473 (2200 ): 20160859 PMID28484329 show ga The ability to create carbon-carbon bonds is at the heart of organic synthesis. Radical processes are particularly apt at creating such bonds, especially in cascade or relay sequences where more than one bond is formed, allowing for a rapid assembly of complex structures. In the present brief overview, examples taken from the authors' laboratory will serve to illustrate the strategic impact of radical-based approaches on synthetic planning. Transformations involving nitrogen-centred radicals, electron transfer from metallic nickel and the reversible degenerative exchange of xanthates will be presented and discussed. The last method has proved to be a particularly powerful tool for the intermolecular creation of carbon-carbon bonds by radical additions even to unactivated alkenes. Various functional groups can be brought into the same molecule in a convergent manner and made to react together in order to further increase the structural complexity. One important benefit of this chemistry is the so-called RAFT/MADIX technology for the manufacture of block copolymers of almost any desired architecture. äSome aspects of radical cascade and relay reactions (epmc).pdf DeepDyve Pubget Overpricing