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10.1002/marc.201600057 http://scihub22266oqcxt.onion/10.1002/marc.201600057 C4907350!4907350 !27027404     free     free     free Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\27027404 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       Macromol+Rapid+Commun 2016 ; 37 (9 ): 769-74 Nephropedia Template TP {{tp|p=27027404 |t=2016. Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes |pdf=|usr=}}{{27027404 }} gab.com Text Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes JO: Macromol Rapid Commun http://www.kidney.de/pget.php?&tw=1&pmid=27027404 #FOAvip A new synthetic procedure is described for the preparation of poly(organo)phosphazenes with star-branched and star dendritic molecular brush type structures, thus describing the first time it has been possible to prepare controlled, highly branched architectures for this type of polymer. Furthermore, as a result of the extremely high-arm density generated by the phosphazene repeat unit, the second-generation structures represent quite unique architectures for any type of polymer. Using two relativity straight forward iterative syntheses it is possible to prepare globular highly branched polymers with up to 30 000 functional end groups, while keeping relatively narrow polydispersities (1.2-1.6). Phosphine mediated polymerization of chlorophosphoranimine is first used to prepare three-arm star polymers. Subsequent substitution with diphenylphosphine moieties gives poly(organo)phosphazenes to function as multifunctional macroinitiators for the growth of a second generation of polyphosphazene arms. Macrosubstitution with Jeffamine oligomers gives a series of large, water soluble branched macromolecules with high-arm density and hydrodynamic diameters between 10 and 70 nm. Twit Text FOAVip Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes ????Macromol Rapid Commun http://www.kidney.de/pget.php?&tw=1&pmid=27027404 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=27027404 #FOAvip English Wikipedia <ref>{{Cite pmid|27027404 }}</ref> Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes #MMPMID27027404 Henke H ; Posch S ; Brüggemann O ; Teasdale I Macromol Rapid Commun 2016[May]; 37 (9 ): 769-74 PMID27027404 show ga A new synthetic procedure is described for the preparation of poly(organo)phosphazenes with star-branched and star dendritic molecular brush type structures, thus describing the first time it has been possible to prepare controlled, highly branched architectures for this type of polymer. Furthermore, as a result of the extremely high-arm density generated by the phosphazene repeat unit, the second-generation structures represent quite unique architectures for any type of polymer. Using two relativity straight forward iterative syntheses it is possible to prepare globular highly branched polymers with up to 30 000 functional end groups, while keeping relatively narrow polydispersities (1.2-1.6). Phosphine mediated polymerization of chlorophosphoranimine is first used to prepare three-arm star polymers. Subsequent substitution with diphenylphosphine moieties gives poly(organo)phosphazenes to function as multifunctional macroinitiators for the growth of a second generation of polyphosphazene arms. Macrosubstitution with Jeffamine oligomers gives a series of large, water soluble branched macromolecules with high-arm density and hydrodynamic diameters between 10 and 70 nm. |Dendrimers/*chemical synthesis/*chemistry [MESH] |Organophosphorus Compounds/*chemical synthesis/*chemistry [MESH]Polyphosphazene Based Star-Branched and Dendritic Molecular Brushes (epmc).pdf DeepDyve Pubget Overpricing