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10.1098/rsta.2014.0322

http://scihub22266oqcxt.onion/10.1098/rsta.2014.0322
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suck abstract from ncbi


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pmid25987571
      Philos+Trans+A+Math+Phys+Eng+Sci 2015 ; 373 (2044 ): ä
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  • Photon upconversion sensitized by a Ru(II)-pyrenyl chromophore #MMPMID25987571
  • Deng F ; Lazorski MS ; Castellano FN
  • Philos Trans A Math Phys Eng Sci 2015[Jun]; 373 (2044 ): ä PMID25987571 show ga
  • The near-visible-to-blue singlet fluorescence of anthracene sensitized by a ruthenium chromophore with a long-lived triplet-excited state, [Ru(5-pyrenyl-1,10-phenanthroline)(3)](PF(6))(2), in acetonitrile was investigated. Low intensity non-coherent green light was used to selectively excite the sensitizer in the presence of micromolar concentrations of anthracene generating anti-Stokes, singlet fluorescence in the latter, even with incident power densities below 500??W?cm(-2). The resultant data are consistent with photon upconversion proceeding from sensitized triplet-triplet annihilation (TTA) of the anthracene acceptor molecules, confirmed through transient absorption spectroscopy as well as static and dynamic photoluminescence experiments. Additionally, quadratic-to-linear incident power regimes for the upconversion process were identified for this composition under monochromatic 488 nm excitation, consistent with a sensitized TTA mechanism ultimately producing the anti-Stokes emission characteristic of anthracene singlet fluorescence.
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