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10.3390/ma4010153

http://scihub22266oqcxt.onion/10.3390/ma4010153
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suck abstract from ncbi


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pmid28879983
      Materials+(Basel) 2011 ; 4 (1 ): 153-168
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  • Multiferroic Compounds with Double-Perovskite Structures #MMPMID28879983
  • Shimakawa Y ; Azuma M ; Ichikawa N
  • Materials (Basel) 2011[Jan]; 4 (1 ): 153-168 PMID28879983 show ga
  • New multiferroic compounds with double-perovskite structures were synthesized. Bi?NiMnO? was synthesized in bulk form by high-pressure synthesis and also in a thin-film form by epitaxial growth. The material showed both ferromagnetic and ferroelectric properties, i.e., the multiferroic property at low temperature. Bi?FeCrO? was also fabricated in a (1 1 1) oriented BiFeO?/BiCrO? artificial superlattice, with a 1/1 stacking period. The superlattice film showed ferromagnetic behavior and polarization switching at room temperature. In the compounds, Bi(3+) ion, located at the A site in the perovskite structure, caused ferroelectric structural distortion, and the B-site ordering of the Ni(2+) and Mn(4+) ions (Fe(3+) and Cr(3+) ions) in a rock-salt configuration led to ferromagnetism according to the Kanamori-Goodenough rule.
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