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10.1038/ncomms15929

http://scihub22266oqcxt.onion/10.1038/ncomms15929
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C5493765!5493765!28660878
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suck abstract from ncbi


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pmid28660878      Nat+Commun 2017 ; 8 (ä): ä
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  • Jahn-Teller distortion driven magnetic polarons in magnetite #MMPMID28660878
  • Huang HY; Chen ZY; Wang R-P; de Groot FMF; Wu WB; Okamoto J; Chainani A; Singh A; Li Z-Y; Zhou J-S; Jeng H-T; Guo GY; Park JG; Tjeng LH; Chen CT; Huang DJ
  • Nat Commun 2017[]; 8 (ä): ä PMID28660878show ga
  • The first known magnetic mineral, magnetite, has unusual properties, which have fascinated mankind for centuries; it undergoes the Verwey transition around 120?K with an abrupt change in structure and electrical conductivity. The mechanism of the Verwey transition, however, remains contentious. Here we use resonant inelastic X-ray scattering over a wide temperature range across the Verwey transition to identify and separate out the magnetic excitations derived from nominal Fe2+ and Fe3+ states. Comparison of the experimental results with crystal-field multiplet calculations shows that the spin?orbital dd excitons of the Fe2+ sites arise from a tetragonal Jahn-Teller active polaronic distortion of the Fe2+O6 octahedra. These low-energy excitations, which get weakened for temperatures above 350?K but persist at least up to 550?K, are distinct from optical excitations and are best explained as magnetic polarons.
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