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Jahn-Teller distortion driven magnetic polarons in magnetite #MMPMID28660878
Huang HY; Chen ZY; Wang R-P; de Groot FMF; Wu WB; Okamoto J; Chainani A; Singh A; Li Z-Y; Zhou J-S; Jeng H-T; Guo GY; Park JG; Tjeng LH; Chen CT; Huang DJ
Nat Commun 2017[]; 8 (ä): ä PMID28660878show ga
The first known magnetic mineral, magnetite, has unusual properties, which have fascinated mankind for centuries; it undergoes the Verwey transition around 120?K with an abrupt change in structure and electrical conductivity. The mechanism of the Verwey transition, however, remains contentious. Here we use resonant inelastic X-ray scattering over a wide temperature range across the Verwey transition to identify and separate out the magnetic excitations derived from nominal Fe2+ and Fe3+ states. Comparison of the experimental results with crystal-field multiplet calculations shows that the spin?orbital dd excitons of the Fe2+ sites arise from a tetragonal Jahn-Teller active polaronic distortion of the Fe2+O6 octahedra. These low-energy excitations, which get weakened for temperatures above 350?K but persist at least up to 550?K, are distinct from optical excitations and are best explained as magnetic polarons.