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10.1038/s41598-018-26205-x

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suck abstract from ncbi


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pmid29789634
      Sci+Rep 2018 ; 8 (1 ): 8005
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  • Giant photovoltaic response in band engineered ferroelectric perovskite #MMPMID29789634
  • Pal S ; Swain AB ; Biswas PP ; Murali D ; Pal A ; Nanda BRK ; Murugavel P
  • Sci Rep 2018[May]; 8 (1 ): 8005 PMID29789634 show ga
  • Recently the solar energy, an inevitable part of green energy source, has become a mandatory topics in frontier research areas. In this respect, non-centrosymmetric ferroelectric perovskites with open circuit voltage (V(OC)) higher than the bandgap, gain tremendous importance as next generation photovoltaic materials. Here a non-toxic co-doped Ba(1-x)(Bi(0.5)Li(0.5)) (x) TiO(3) ferroelectric system is designed where the dopants influence the band topology in order to enhance the photovoltaic effect. In particular, at the optimal doping concentration (x (opt) ?~?0.125) the sample reveals a remarkably high photogenerated field E(OC)?=?320?V/cm (V(OC)?=?16?V), highest ever reported in any bulk polycrystalline non-centrosymmetric systems. The band structure, examined through DFT calculations, suggests that the shift current mechanism is key to explain the large enhancement in photovoltaic effect in this family.
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