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10.1126/sciadv.1603224

http://scihub22266oqcxt.onion/10.1126/sciadv.1603224
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suck abstract from ncbi


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pmid28508051
      Sci+Adv 2017 ; 3 (4 ): e1603224
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  • Genuine binding energy of the hydrated electron #MMPMID28508051
  • Luckhaus D ; Yamamoto YI ; Suzuki T ; Signorell R
  • Sci Adv 2017[Apr]; 3 (4 ): e1603224 PMID28508051 show ga
  • The unknown influence of inelastic and elastic scattering of slow electrons in water has made it difficult to clarify the role of the solvated electron in radiation chemistry and biology. We combine accurate scattering simulations with experimental photoemission spectroscopy of the hydrated electron in a liquid water microjet, with the aim of resolving ambiguities regarding the influence of electron scattering on binding energy spectra, photoelectron angular distributions, and probing depths. The scattering parameters used in the simulations are retrieved from independent photoemission experiments of water droplets. For the ground-state hydrated electron, we report genuine values devoid of scattering contributions for the vertical binding energy and the anisotropy parameter of 3.7 ± 0.1 eV and 0.6 ± 0.2, respectively. Our probing depths suggest that even vacuum ultraviolet probing is not particularly surface-selective. Our work demonstrates the importance of quantitative scattering simulations for a detailed analysis of key properties of the hydrated electron.
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