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10.1002/cssc.201700679

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pmid28644559
      ChemSusChem 2017 ; 10 (15 ): 3049-3055
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  • Evaluating Dihydroazulene/Vinylheptafulvene Photoswitches for Solar Energy Storage Applications #MMPMID28644559
  • Wang Z ; Udmark J ; Börjesson K ; Rodrigues R ; Roffey A ; Abrahamsson M ; Nielsen MB ; Moth-Poulsen K
  • ChemSusChem 2017[Aug]; 10 (15 ): 3049-3055 PMID28644559 show ga
  • Efficient solar energy storage is a key challenge in striving toward a sustainable future. For this reason, molecules capable of solar energy storage and release through valence isomerization, for so-called molecular solar thermal energy storage (MOST), have been investigated. Energy storage by photoconversion of the dihydroazulene/vinylheptafulvene (DHA/VHF) photothermal couple has been evaluated. The robust nature of this system is determined through multiple energy storage and release cycles at elevated temperatures in three different solvents. In a nonpolar solvent such as toluene, the DHA/VHF system can be cycled more than 70?times with less than 0.01?% degradation per cycle. Moreover, the [Cu(CH(3) CN)(4) ]PF(6) -catalyzed conversion of VHF into DHA was demonstrated in a flow reactor. The performance of the DHA/VHF couple was also evaluated in prototype photoconversion devices, both in the laboratory by using a flow chip under simulated sunlight and under outdoor conditions by using a parabolic mirror. Device experiments demonstrated a solar energy storage efficiency of up to 0.13?% in the chip device and up to 0.02?% in the parabolic collector. Avenues for future improvements and optimization of the system are also discussed.
  • |*Lab-On-A-Chip Devices [MESH]
  • |*Photochemical Processes [MESH]
  • |*Solar Energy [MESH]
  • |Azulenes/*chemistry [MESH]


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