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10.1021/jz4016553 http://scihub22266oqcxt.onion/10.1021/jz4016553 C4047568!4047568!24920995     free     free     free Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\24920995.jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       J+Phys+Chem+Lett 2013 ; 4 (17): 2970-4 Nephropedia Template TP {{tp|p=24920995|t=2013. Ether-Bond-Containing Ionic Liquids as Supercapacitor Electrolytes |pdf=|usr=}}{{24920995}} gab.com Text Ether-Bond-Containing Ionic Liquids as Supercapacitor Electrolytes JO: J Phys Chem Lett http://www.kidney.de/pget.php?&tw=1&pmid=24920995 #FOAvip Electrochemical capacitors (ECs) are electrical energy storage devices that have the potential to be very useful in a wide range of applications, especially where there is a large disparity between peak and average power demands. The use of ionic liquids (ILs) as electrolytes in ECs can increase the energy density of devices; however, the viscosity and conductivity of ILs adversely influence the power density of the device. We present experimental results where several ILs containing different cations have been employed as the electrolyte in cells containing mesoporous carbon electrodes. Specifically, the behavior of ILs containing an ether bond in an alkyl side chain are compared with those of a similar structure and size but containing purely alkyl side chains. Using electrochemical impedance spectroscopy and constant current cycling, we show that the presence of the ether bond can dramatically increase the specific capacitance and reduce device resistance. These results have the important implication that such ILs can be used to tailor the physical properties and electrochemical performance of IL-based electrolytes. Twit Text FOAVip Ether-Bond-Containing Ionic Liquids as Supercapacitor Electrolytes ????J Phys Chem Lett http://www.kidney.de/pget.php?&tw=1&pmid=24920995 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=24920995 #FOAvip English Wikipedia <ref>{{Cite pmid|24920995}}</ref> Ether-Bond-Containing Ionic Liquids as Supercapacitor Electrolytes #MMPMID24920995 Rennie AJR; Sanchez-Ramirez N; Torresi RM; Hall PJ J Phys Chem Lett 2013[Sep]; 4 (17): 2970-4 PMID24920995show ga Electrochemical capacitors (ECs) are electrical energy storage devices that have the potential to be very useful in a wide range of applications, especially where there is a large disparity between peak and average power demands. The use of ionic liquids (ILs) as electrolytes in ECs can increase the energy density of devices; however, the viscosity and conductivity of ILs adversely influence the power density of the device. We present experimental results where several ILs containing different cations have been employed as the electrolyte in cells containing mesoporous carbon electrodes. Specifically, the behavior of ILs containing an ether bond in an alkyl side chain are compared with those of a similar structure and size but containing purely alkyl side chains. Using electrochemical impedance spectroscopy and constant current cycling, we show that the presence of the ether bond can dramatically increase the specific capacitance and reduce device resistance. These results have the important implication that such ILs can be used to tailor the physical properties and electrochemical performance of IL-based electrolytes. äEther-Bond-Containing Ionic Liquids as Supercapacitor Electrolytes (epmc).pdf DeepDyve Pubget Overpricing