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2016 ; 7
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Electron-phonon coupling in hybrid lead halide perovskites
#MMPMID27225329
Wright AD
; Verdi C
; Milot RL
; Eperon GE
; Pérez-Osorio MA
; Snaith HJ
; Giustino F
; Johnston MB
; Herz LM
Nat Commun
2016[May]; 7
(ä): ä PMID27225329
show ga
Phonon scattering limits charge-carrier mobilities and governs emission line
broadening in hybrid metal halide perovskites. Establishing how charge carriers
interact with phonons in these materials is therefore essential for the
development of high-efficiency perovskite photovoltaics and low-cost lasers. Here
we investigate the temperature dependence of emission line broadening in the four
commonly studied formamidinium and methylammonium perovskites, HC(NH2)2PbI3,
HC(NH2)2PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from
longitudinal optical phonons via the Fröhlich interaction is the dominant source
of electron-phonon coupling near room temperature, with scattering off acoustic
phonons negligible. We determine energies for the interacting longitudinal
optical phonon modes to be 11.5 and 15.3?meV, and Fröhlich coupling constants of
?40 and 60?meV for the lead iodide and bromide perovskites, respectively. Our
findings correlate well with first-principles calculations based on many-body
perturbation theory, which underlines the suitability of an electronic
band-structure picture for describing charge carriers in hybrid perovskites.