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2016 ; 113
(36
): 10007-12
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Electron anions and the glass transition temperature
#MMPMID27559083
Johnson LE
; Sushko PV
; Tomota Y
; Hosono H
Proc Natl Acad Sci U S A
2016[Sep]; 113
(36
): 10007-12
PMID27559083
show ga
Properties of glasses are typically controlled by judicious selection of the
glass-forming and glass-modifying constituents. Through an experimental and
computational study of the crystalline, molten, and amorphous
[Ca12Al14O32](2+)???(e(-))2, we demonstrate that electron anions in this system
behave as glass modifiers that strongly affect solidification dynamics, the glass
transition temperature, and spectroscopic properties of the resultant amorphous
material. The concentration of such electron anions is a consequential control
parameter: It invokes materials evolution pathways and properties not available
in conventional glasses, which opens a unique avenue in rational materials
design.