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10.1039/C4SC03516J http://scihub22266oqcxt.onion/10.1039/C4SC03516J C4335805!4335805 !25709805     free     free     free Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Deprecated: Implicit conversion from float 209.6 to int loses precision in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 534 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\25709805 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       Chem+Sci 2015 ; 6 (3 ): 1979-1985 Nephropedia Template TP {{tp|p=25709805 |t=2015. Chemiluminescent Probes for Imaging H(2)S in Living Animals |pdf=|usr=}}{{25709805 }} gab.com Text Chemiluminescent Probes for Imaging H(2)S in Living Animals JO: Chem Sci http://www.kidney.de/pget.php?&tw=1&pmid=25709805 #FOAvip Hydrogen sulphide (H(2)S) is an endogenous mediator of human health and disease, but precise measurement in living cells and animals remains a considerable challenge. We report the total chemical synthesis and characterization of three 1,2-dioxetane chemiluminescent reaction-based H(2)S probes, CHS-1, CHS-2, and CHS-3. Upon treatment with H(2)S at physiological pH, these probes display instantaneous light emission that is sustained for over an hour with high selectivity against other reactive sulphur, oxygen, and nitrogen species. Analysis of the phenol/phenolate equilibrium and atomic charges has provided a generally applicable predictive model to design improved chemiluminescent probes. The utility of these chemiluminescent reagents was demonstrated by applying CHS-3 to detect cellularly generated H(2)S using a multi-well plate reader and to image H(2)S in living mice using CCD camera technology. Twit Text FOAVip Chemiluminescent Probes for Imaging H(2)S in Living Animals ????Chem Sci http://www.kidney.de/pget.php?&tw=1&pmid=25709805 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=25709805 #FOAvip English Wikipedia <ref>{{Cite pmid|25709805 }}</ref> Chemiluminescent Probes for Imaging H(2)S in Living Animals #MMPMID25709805 Cao J ; Lopez R ; Thacker JM ; Moon JY ; Jiang C ; Morris SN ; Bauer JH ; Tao P ; Mason RP ; Lippert AR Chem Sci 2015[Mar]; 6 (3 ): 1979-1985 PMID25709805 show ga Hydrogen sulphide (H(2)S) is an endogenous mediator of human health and disease, but precise measurement in living cells and animals remains a considerable challenge. We report the total chemical synthesis and characterization of three 1,2-dioxetane chemiluminescent reaction-based H(2)S probes, CHS-1, CHS-2, and CHS-3. Upon treatment with H(2)S at physiological pH, these probes display instantaneous light emission that is sustained for over an hour with high selectivity against other reactive sulphur, oxygen, and nitrogen species. Analysis of the phenol/phenolate equilibrium and atomic charges has provided a generally applicable predictive model to design improved chemiluminescent probes. The utility of these chemiluminescent reagents was demonstrated by applying CHS-3 to detect cellularly generated H(2)S using a multi-well plate reader and to image H(2)S in living mice using CCD camera technology. äChemiluminescent Probes for Imaging H(2)S in Living Animals (epmc).pdf DeepDyve Pubget Overpricing