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10.1038/s41598-017-08551-4

http://scihub22266oqcxt.onion/10.1038/s41598-017-08551-4
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C5570936!5570936 !28839222
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suck abstract from ncbi


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pmid28839222
      Sci+Rep 2017 ; 7 (1 ): 8088
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  • Cesium ion detection by terahertz light #MMPMID28839222
  • Ohkoshi SI ; Yoshikiyo M ; Namai A ; Nakagawa K ; Chiba K ; Fujiwara R ; Tokoro H
  • Sci Rep 2017[Aug]; 7 (1 ): 8088 PMID28839222 show ga
  • Recent developments in terahertz technologies provide new tools for analysis, inspection, and nondestructive sensing. If a heavy atom is encapsulated in a cage of a porous material, the atom should vibrate slowly and resonate with a low-frequency terahertz light. From this perspective, a cyanide-bridged metal framework is a suitable system because it contains many cages that can adsorb Cs ions. Herein we show the vibration mode of a Cs ion in a cage of a cyanide-bridged metal framework. First-principles phonon mode calculations and terahertz time-domain spectroscopy (THz-TDS) measurements indicate that the vibration mode of a Cs ion in a cyanide-bridged manganese-iron framework is at 1.5?THz, which is significantly apart from other lattice vibrations. Taking advantage of this feature, we develop a THz-light detection method for Cs ions, which is useful for non-contact sensing of Cs ions in dangerous environments or harmful circumstances.
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