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10.1038/s41467-025-64209-0 http://scihub22266oqcxt.onion/10.1038/s41467-025-64209-0 C12533082!12533082 !41102165     free     free     free Warning: file_get_contents(https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&id=41102165 &cmd=llinks): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 215 Warning: imagejpeg(C:\Inetpub\vhosts\kidney.de\httpdocs\phplern\41102165 .jpg): Failed to open stream: No such file or directory in C:\Inetpub\vhosts\kidney.de\httpdocs\pget.php on line 117       Nat+Commun 2025 ; 16 (1 ): 9181 Nephropedia Template TP {{tp|p=41102165 |t=2025. 1,1-polymerization of acetylene |pdf=|usr=}}{{41102165 }} gab.com Text 1,1-polymerization of acetylene JO: Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=41102165 #FOAvip The polymerization of alkynes has long been a cornerstone of materials science, yielding a plethora of ?-bond-rich materials and underpinning the 2000 Nobel Prize in Chemistry. While 1,2-polymerization of alkynes via 1,2-addition has been extensively studied, the 1,1-polymerization of carbon carbon triple bonds remains a formidable challenge due to the necessity of an alkyne rearrangement step during polymerization. Here we report the 1,1-polymerization of acetylene gas through a Cd-catalyzed iterative 1,1-carboboration process, achieving a broad terminal functionalization scope and functional group compatibility. This product, 1,1-polyacetylene (1,1-PA), also named as dendralene, exhibits unique physical and chemical properties, including an explosive tendency, distinguishing it from the 1,2-polyacetylene (1,2-PA) counterparts. Twit Text FOAVip 1,1-polymerization of acetylene ????Nat Commun http://www.kidney.de/pget.php?&tw=1&pmid=41102165 #FOAvip Twit Text # Free Paper on # # # # # LINK http://www.kidney.de/pget.php?&tw=1&pmid=41102165 #FOAvip English Wikipedia <ref>{{Cite pmid|41102165 }}</ref> 1,1-polymerization of acetylene #MMPMID41102165 Cheng T ; Qiu J ; Yang Z ; Li S ; Jiang H ; Zhu S Nat Commun 2025[Oct]; 16 (1 ): 9181 PMID41102165 show ga The polymerization of alkynes has long been a cornerstone of materials science, yielding a plethora of ?-bond-rich materials and underpinning the 2000 Nobel Prize in Chemistry. While 1,2-polymerization of alkynes via 1,2-addition has been extensively studied, the 1,1-polymerization of carbon carbon triple bonds remains a formidable challenge due to the necessity of an alkyne rearrangement step during polymerization. Here we report the 1,1-polymerization of acetylene gas through a Cd-catalyzed iterative 1,1-carboboration process, achieving a broad terminal functionalization scope and functional group compatibility. This product, 1,1-polyacetylene (1,1-PA), also named as dendralene, exhibits unique physical and chemical properties, including an explosive tendency, distinguishing it from the 1,2-polyacetylene (1,2-PA) counterparts. ä1,1-polymerization of acetylene (epmc).pdf DeepDyve Pubget Overpricing