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lüll What have we learnt about heavy carbenes through laser flash photolysis studies?Becerra R; Walsh RPhys Chem Chem Phys 2007[Jun]; 9 (22): 2817-35Time resolved gas-phase kinetic studies have contributed a great deal of fundamental information about the reactions and reactivity of heavy carbenes (silylenes, germylenes and stannylenes) during the past two decades. In this article we trace the development of our understanding through the mechanistic themes of intermediate complexes, third body assisted associations, catalysed reactions, non-observed reactions and substituent effects. Ab initio (quantum chemical) calculations have substantially assisted mechanistic interpretation and are discussed where appropriate. Trends in reactivity are identified and some signposts to future studies are indicated. This review, although detailed, is not comprehensive.|*Lasers[MESH]|*Models, Chemical[MESH]|*Models, Molecular[MESH]|*Photolysis[MESH]|Computer Simulation[MESH]|Forecasting[MESH]|Hydrocarbons/chemistry/radiation effects[MESH]|Methane/*analogs & derivatives/chemistry/radiation effects[MESH] |