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Quantum catalysis in enzymes: beyond the transition state theory paradigm A Discussion Meeting held at the Royal Society on 14 and 15 November 2005 Scrutton NS; Sutcliffe MJ; Leslie Dutton PJ R Soc Interface 2006[Jun]; 3 (8): 465-9How do enzymes work? What is the physical basis of the phenomenal rate enhancements achieved by enzymes? Do we have a theoretical framework that accounts for observed catalytic rates? These are the foremost questions-with particular emphasis on tunnelling phenomena-debated at this Discussion Meeting by the leading practitioners in the field.|*Biocatalysis[MESH]|Computer Simulation[MESH]|Electrons[MESH]|Enzymes/chemistry/*physiology[MESH]|Hydrogen/chemistry[MESH]|Kinetics[MESH]|Models, Chemical[MESH]|Oxidation-Reduction[MESH]|Quantum Theory[MESH] |
